L-(-)-Menthol in the Synthesis of Key Synthons for Optically Active Methyl-Branched Insect Pheromones
摘要：
A synthesis of optically active 4S-methylhexanal, 1-bromo-3S-methylheptane, and 1-bromo-3S-methylundecane, which are key synthons for several methyl-branched insect pheromones, that is based on chemically selective transformations of 6-tosyloxy- and 6-iodoisopropyl-4R-methylhexanoates that are available from L-(-)-menthol was proposed.
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关键词：
L ( ) menthol 6 tosyloxy and 6 iodoisopropyl 4R methylhexanoates 4S methylhexanal 1 bromo 3S methylheptane 1 bromo 3S methylundecane insect pheromones synthon synthesis
DOI：
10.1007/s10600-006-0019-4
被引量：
年份：
2005
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