New Sulfur‐ and Selenium‐Bridged Copper Clusters; Ab Initio Calculations on [Cu2nSen(PH3)m] Clusters
摘要：
Reaction of copper(I) acetate with bis(trimethylsilyl)chalcogenides E-(SiMe3)2 (E = S, Se) in the presence of tertiary phosphines in organic solvents leads to the formation of chalcogenbridged copper clusters in crystalline form. In recent investigations, the following structures were isolated and characterised by X-ray crystallography: [Cu24S12-(PMeiPr2)12] (1), [Cu28S14(PtBu2Me)12] (2),...
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DOI：
10.1002/anie.199407461
被引量：
年份：
1994
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