An approach toward the total synthesis of cyclotheonamides; preparation of a C(1) to N(14) segment
摘要：
The C(1) to N(14) segment of the potent thrombin inhibitor cyclotheonamide A was prepared from L-arginine, L-proline, and L-asparagine. The arginine backbone was extended via a cyanohydrin, and the usual diaminopropanoic acid residue was obtained from hypervalent iodine oxidation of the asparagine side chain.
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关键词：
DNA OLIGONUCLEOTIDE AUTOMATED SYNTHESIS 8-BROMO-2'-DEOXYADENOSINE PHENOXYACETYL PROTECTING GROUP DNA DUPLEX STABILITY
DOI：
10.1016/S0040-4039(00)74237-7
被引量：
年份：
1992
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