Organopalladium halides, acetates, triflates and similar derivatives lacking 尾 sp 3 -bonded hydrogens generally react easily with unhindered alkenes to form new alkenes in which an original, vinyl hydrogen is replaced by the organic gro...
Palladium-catalyzed coupling of haloarenes by Heck-, Suzuki-, Sonogashira-, and Stille-type reactions is a widely used methodology in modem organic synthes...
R. F. Heck, Palladium Reagents in Organic Syntheses; (Katritzky, A. R., Meth- Cohn O., Rees, C. W., Eds.; Academic Press: London, 1985; p 2.) b) Heck, R. F. Vinyl Substitution with Organopalladium Intermediates. In ...
Nelson，John H. - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Arynes are among the most intensively studied systems in chemistry. However, many aspects of the chemistry of these reactive intermediates are not well und...
The +IV Oxidation State in Organopalladium Chemistry Automobile Emissions to be Restricted Further The Platinum Catalysed Reduction of Nitric Oxide by Ammo...
Arynes are among the most intensively studied systems in chemistry. However, many aspects of the chemistry of these reactive intermediates are not well und...
Arynes are among the most intensively studied systems in chemistry. However, many aspects of the chemistry of these reactive intermediates are not well und...
Organopalladium derivatives are useful intermediates in organic synthesis1. Palladium (II) salts catalyze cyclization of acetylenic 1,2-diols2, γ,β-unsat...
Transition metal complex-catalyzed organosulfur chemistry leading to selective formation of carbon-sulfur bonds is reviewed with an emphasis on recent prog...
Transition metal complex-catalyzed organosulfur chemistry leading to selective formation of carbon-sulfur bonds is reviewed with an emphasis on recent prog...
Allylic alkylation requires activation of the allylic C-H bond and formation of a C-C bond. A mild way for achieving this activation is developed. A genera...
Alkenyl halides react with organolithium compounds, such as alkyl, aryl, and heterocyclic lithiums, in the presence of zerovalent palladium compounds to fo...
Unsymmetrical allyl-allyl couplings occur between allylstannanes and allyl acetates catalyzed by palladium(O) and a novel direct coupling of an allyl aceta...
The first electrophilic Pd(II)-catalyzed allylic C—H alkylation is reported, providing a novel method for formation of sp3sp3 C—C bonds directly from C—...
Strain in small rings has evolved as one of the principles used to control reactivity and chemoselectivity in transformations of organic compounds. The com...
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a Chem...
Nickel-catalyzed intermolecular allylic substitution of simple alkenes (ethylene and alpha olefins) is described. This method is the first catalytic interm...
