New type phosphorous amides derived from protected monosaccharides
摘要：
Three synthetic routes to hydrogen phosphoramidites derived from protected hydrocarbons containing one free secondary hydroxy group are explored: phosphorylation with (diethylamido)phosphorous dichloride, acidolysis of tetraalkyldiamides derived from sugars, and phosphorylation with phosphorous tetraalkyldiamides. The last route was found to be preferred. Some properties of the prepared dialkylamidoglycophosphites were studied: stability, phosphorylating activity, and behavior in oxidation reactions.
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DOI：
10.1134/S1070363206040062
被引量：
年份：
2006
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