Synthesis and characterization of two copper cyanide complexes with hexagonal Cu6 units
摘要:
Reaction of CuCN with PPh3 and PPh4Br induced by the pyridine-2-thiolate anion in DMF resulted in a discrete hexanuclear [Cu(CN)(PPh3)2]6 (1) complex with a large hexagonal cavity and a polymer [(PPh4){Cu2(CN)3}]n (2) with a graphite-like lamellar structure, respectively.
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DOI:
10.1039/B002096F
被引量:
年份:
2000
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来源期刊
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2005
被引量:17
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