Liquid electrolyte lithium-sulfur batteries

阅读量:

29

申请(专利)号:

CA19982305454

申请日期:

1998-10-06

公开/公告号:

CA2305454A1

公开/公告日期:

1999-04-22

申请(专利权)人:

POLYPLUS BATTERY COMPANY

发明人:

MY ChuLCD JongheSJ ViscoBD Katz

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被引量:

245

摘要:

Disclosed are electrolyte solvents for ambient-temperature lithium- sulfur batteries. The disclosed solvents include at least one ethoxy repeating unit compound of the general formula R.sub.1 (CH.sub.2 CH.sub. 2 O).sub.n R.sub.2, where n ranges between 2 and 10 and R.sub.1 and R. sub.2 are different or identical alkyl or alkoxy groups (including substituted alkyl or alkoxy groups). Alternatively, R.sub.1 and R.sub.2 may together with (CH.sub.2 CH.sub.2 O).sub.n form a closed ring. Examples of linear solvents include the glymes (CH.sub.3 O(CH.sub.2 CH. sub.2).sub.n CH.sub.3). Some electrolyte solvents include a donor or acceptor solvent in addition to an ethoxy compound as described. Examples of donor solvents include hexamethylphosphoramide, pyridine, N, N- diethylacetamide, N,N-diethylformamide, dimethylsulfoxide, tetramethylurea, N,N-dimethylacetamide, N,N-dimethylformamide, tributylphosphate, trimethylphosphate, N,N,N',N'-tetraethylsulfamide, tetramethylenediamine, tetramethylpropylenediamine, and pentamethyldiethylenetriamine. These assist in solvation of lithium ions. Examples of acceptor solvents include alcohols, glycols, and polyglycols. These assist in solvation of the sulfide and polysulfide anions.

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