A New Copper Acetate-Bis(oxazoline)-Catalyzed, Enantioselective Henry Reaction
摘要：
A highly enantioselective, nitroaldol reaction catalyzed by a chiral Cu(II) bis(oxazoline) complex has been developed. The reaction scope includes both aromatic and aliphatic aldehydes (15 examples) affording products in good yields and enantioselectivities (87-94% ee). An X-ray structure of the catalyst has been provided along with a rationalization of the sense of asymmetric induction.
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关键词：
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) addition reactions nitro alcohols alcohols (benzene compounds)
DOI：
10.1002/chin.200407041
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年份：
2003
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