A New Copper Acetate-Bis(oxazoline)-Catalyzed, Enantioselective Henry Reaction
摘要：
A highly enantioselective, nitroaldol reaction catalyzed by a chiral Cu(II) bis(oxazoline) complex has been developed. The reaction scope includes both aromatic and aliphatic aldehydes (15 examples) affording products in good yields and enantioselectivities (87-94% ee). An X-ray structure of the catalyst has been provided along with a rationalization of the sense of asymmetric induction.
展开
关键词：
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) addition reactions nitro alcohols alcohols (benzene compounds)
DOI：
10.1002/chin.200407041
被引量：
年份：
2003
Wiley
ACS
(全网免费下载)
ACS
万方医学
Semantic Scholar
查看更多
Semantic Scholar
(全网免费下载)
dx.doi.org
NCBI
NCBI
Europe PMC
ResearchGate
ResearchGate
(全网免费下载)
Citeseer
EBSCO
Citeseer
(全网免费下载)
mendeley.com
ucdavis.pure.elsevier.com
organic-chemistry.org
cheric.org
pubfacts.com
evans.rc.fas.harvard.edu
(全网免费下载)
people.bu.edu
(全网免费下载)
scienceopen.com
www2.lsdiv.harvard.edu
(全网免费下载)
pubget.com
ACS
(全网免费下载)
Semantic Scholar
(全网免费下载)
ResearchGate
(全网免费下载)
Citeseer
(全网免费下载)
people.bu.edu
(全网免费下载)
evans.rc.fas.harvard.edu
(全网免费下载)
www2.lsdiv.harvard.edu
(全网免费下载)
通过文献互助平台发起求助，成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
来源期刊
研究点推荐
引用走势
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
