Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with Alkyl P-Donor Ligands on Rhodium Using a Peracetylated β-Cyclodextrin as a Solubiliser
摘要:
The presence of peracetylated β-cyclodextrin in the reaction medium allowed for an increase in the solubility of rhodium species modified by alkyl P-donor ligands in the catalytic hydroformylation of 1-octene in supercritical carbon dioxide. These results were explained by considering an interaction between the peracetylated β-cyclodextrin and the P-donor ligands.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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DOI:
10.1002/ejic.200800153
被引量:
年份:
2008
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