Thermally irreversible photochromic systems. A theoretical study

阅读量:

123

作者:

S NakamuraM Irie

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摘要:

A new sensitivity analysis technique is developed by utilizing Tihonov's singular perturbation theory. The described sensitivity analysis method deals with algebraic equations instead of solving the system of differential equations, which is the case in conventional sensitivity analysis. In the field of chemical kinetics, the proposed technique can supply information on the importance of elementary steps in complex reaction mechanisms. As examples, high-temperature propane pyrolysis and the chemistry of the "unpolluted" troposphere are studied.

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DOI:

10.1021/jo00261a035

被引量:

1169

年份:

1988

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