The Reaction between Ferrous Iron and Peroxides. II. Reaction with Hydrogen Peroxide, in the Presence of Oxygen

来自 ACS

阅读量:

73

作者:

IM KolthoffAI Medalia

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摘要:

The iron(II)-hydrogen peroxide couple induces the oxidation of arsenic(III). The mechanism, involving the intermediate formation of arsenic(IV), is similar to that in the induced oxidation of arsenic(III) by the iron(II)-persulfate couple and the photoreduction of iron(III). From the results of a study of the induced oxidation of arsenic(III) at 25° the ratio of the rate constants of the...

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DOI:

10.1021/ja01179a058

被引量:

570

年份:

2002

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2010
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