The Reaction between Ferrous Iron and Peroxides. II. Reaction with Hydrogen Peroxide, in the Presence of Oxygen
摘要:
The iron(II)-hydrogen peroxide couple induces the oxidation of arsenic(III). The mechanism, involving the intermediate formation of arsenic(IV), is similar to that in the induced oxidation of arsenic(III) by the iron(II)-persulfate couple and the photoreduction of iron(III). From the results of a study of the induced oxidation of arsenic(III) at 25° the ratio of the rate constants of the...
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DOI:
10.1021/ja01179a058
被引量:
年份:
2002
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