Native Cellulose: A Composite of Two Distinct Crystalline Forms
摘要:
Multiplicities in the resonances of chemically equivalent carbons, which appear in the solid-state carbon-13 nuclear magnetic resonance spectra of native celluloses, have been examined at high resolution. The patterns of variation are consistent with the existence of two distinct crystalline forms. One form is dominant in bacterial and algal celluloses, whereas the other is dominant in celluloses from higher plants.
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关键词:
Experimental/ macromolecular configurations macromolecular spectra molecular biophysics nuclear magnetic resonance/ 13C NMR spectra bacteria algae crystalline forms native celluloses higher plants/ A3620H Macromolecular configuration (bonds, dimensions) A3620K Electronic structure and spectra of macromolecules A8715B Biomolecular structure, configuration, conformation, and active sites A8715M Interactions with radiations at the biomolecular level
DOI:
10.1126/science.223.4633.283
被引量:
年份:
1984
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