Asymmetric Organocatalytic Henry Reaction
摘要:
The nitroaldol (Henry) reaction between aromatic aldehydes and nitromethane can be carried out in high yields and enantiomeric excess by using a novel Cinchona‐derived thiourea catalyst. Hydrogen‐bond donors at the C6′ position in these organocatalysts are shown to induce preferential formation of one enantiomer.
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DOI:
10.1002/anie.200503724
被引量:
年份:
2005
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