Asymmetric Organocatalytic Henry Reaction

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阅读量:

62

作者:

T MarcelliRNSVD HaasJHV MaarseveenH Hiemstra

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摘要:

The nitroaldol (Henry) reaction between aromatic aldehydes and nitromethane can be carried out in high yields and enantiomeric excess by using a novel Cinchona‐derived thiourea catalyst. Hydrogen‐bond donors at the C6′ position in these organocatalysts are shown to induce preferential formation of one enantiomer.

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DOI:

10.1002/anie.200503724

被引量:

890

年份:

2005

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2011
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