Neues über den Mechanismus der retentiven Substitution am Dreiring von Propellanen. Vorlufige Mitteilung
摘要：
New results concerning the mechanism of retentive substitution at the three membered ring of propellanes The reaction of the endo - and exo -bromide 1a and 1b with acetate ion in aprotic polar solvents carried out at high concentrations of 1 furnishes the dimeric dehydro-halogenation products 3a and 3b , the structures of which are determined by x-ray crystallography ( Fig. 1 ). The formation of 3a and 3b as well as of the products 2 of a retentive substitution process can be explained by assuming that the strained benzo-tropones 4 are intermediates. Their high barrier to inversion is confirmed by π-SCF-molecular mechanics calculations.
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DOI：
10.1002/hlca.19770600402
被引量：
年份：
1977
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