Total Synthesis of (±)〩alomon by a Johnson–Claisen Rearrangement
摘要：
The total synthesis of the polyhalogenated antitumour agent halomon (1) was accomplished with two novel transformations as key steps: a Johnson–Claisen rearrangement of a dichlorinated alkene for the preparation of the tertiary chlorinated C3 and a new rearrangement of bromohydrins for the regiospecific introduction of the bromine and chlorine atoms on C6 and C7, respectively.
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DOI：
10.1002/(SICI)1521-3773(19980817)37:153.0.CO;2-J
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年份：
1998
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来源期刊
Angewandte Chemie International Edition
1998/08/17
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2010
被引量：23
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