Water in Stereoselective Organocatalytic Reactions
摘要：
In this review, recent advances in asymmetric organocatalytic reactions carried out with variable amounts of water, from substoichiometric to a large excess (reaction medium), are discussed. We also summarize several proposed mechanisms for the different possibilities of the action of water both in the increased activity of the catalyst and in the asymmetric induction. Finally, the application of this catalytic methodology to the enantioselective synthesis of valuable compounds through enamine or iminium catalysis is presented.
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DOI：
10.1002/adsc.200800731
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年份：
2009
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来源期刊
Advanced Synthesis & Catalysis
2010/5/7 0:00:00
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2010
被引量：136
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