Efficient synthesis of D-erythro-sphingosine and D-erythro-azidosphingosine from D-ribo-phytosphingosine via a cyclic sulfate intermediate.
摘要：
The synthesis of naturally occurring d-erythro-sphingosine and synthetically useful D-erythro-2-azidosphingosine from commercially available d-ribo-phytosphingosine is described. An important feature of this synthesis is the selective transformation of the 3,4-vicinal diol of phytosphingosine into the characteristic E-allylic alcohol of sphingosine via a cyclic sulfate intermediate.
展开
关键词：
ALPHA-GALACTOSYL CERAMIDE CROSS-METATHESIS APPROACH GLYCOSPHINGOLIPID PRECURSORS STEREOSELECTIVE SYNTHESIS ORGANIC-SYNTHESIS ACID PANCRATISTATIN SPHINGOLIPIDS THERAPEUTICS DERIVATIVES
DOI：
10.1021/jo0614543
被引量：
年份：
2006
国家科技图书文献中心
(权威机构)
ACS
ACS
(全网免费下载)
万方医学
掌桥科研
查看更多
Europe PMC
NCBI
ResearchGate
EBSCO
EBSCO
mendeley.com
bvsalud.org
mysciencework.com
pubfacts.com
ACS
(全网免费下载)
通过文献互助平台发起求助，成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
