Photocatalytic Synthesis of Glycosyl Bromides
摘要:
Sugar hemiacetals were smoothly transformed into the corresponding glycosyl bromides by treatment with carbon tetrabromide inN,N-dimethylformamide with tris(2,2′-bipyridyl)ruthenium(II) chloride as a catalyst under visible-light irradiation. Protecting groups commonly used in carbohydrate derivatives are unaffected by the mild conditions for bromination.
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DOI:
10.1055/s-0033-1340493
被引量:
年份:
2014
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SYNTHESIS-STUTTGART
20140203
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