Photocatalytic Synthesis of Glycosyl Bromides

阅读量:

15

作者:

X YuanS ChengY ShiW Xue

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摘要:

Sugar hemiacetals were smoothly transformed into the corresponding glycosyl bromides by treatment with carbon tetrabromide inN,N-dimethylformamide with tris(2,2′-bipyridyl)ruthenium(II) chloride as a catalyst under visible-light irradiation. Protecting groups commonly used in carbohydrate derivatives are unaffected by the mild conditions for bromination.

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DOI:

10.1055/s-0033-1340493

被引量:

1

年份:

2014

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