High‐Temperature Equilibrium in the Germanium—Nickel System and the Dissociation Energy of GeNi
摘要：
The GeNi molecule has been shown to exist in the vapor phase over liquid solutions of germanium and nickel above 2000°K. Using information derived from a combination of effusion and mass‐spectrometric techniques, the energies and equilibrium constants of the gaseous reactions GeNi+Ge=Ge2+Ni and GeNi=Ge+Ni have been calculated. The values of the energy assuming a1Σ ground state of GeNi areGeNi+Ge=Ge2+NiΔE0∘=1.6±4kcal,GeNi=Ge+NiD0∘(GeNi)=66.4±4kcal. The dissociation energy of Ge2was also determined and the value ofD0°(Ge2) of 64.9±3 kcal confirms results obtained previously.
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DOI：
10.1063/1.1727063
被引量：
年份：
1966
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1968
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