An improved Bessel uniform approximation of non-integer order for use in semiclassical collision theory: application to vibrationally inelastic molecular collisions

阅读量:

15

作者:

Connor, J. N. LSouthall, W. J. E

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摘要:

A new choice for the order of the semiclassical noninteger Bessel uniform approximation is proposed and used to calculate transition probabilities for collinear atom-oscillator collisions. Calculations have been performed for two collision systems: a Morse oscillator interacting via an exponential potential and a harmonic oscillator interacting via a Lennard-Jones potential. Results are reported for both classically allowed and classically forbidden transitions. The new noninteger Bessel approximation remains accurate in situations where earlier uniform approximations break down.

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DOI:

10.1021/j100407a027

被引量:

6

年份:

1986

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