An approach towards the C 1 –C 16 fragment of antineoplastic macrolide bryostatins by kinetic resolution of a racemic terminal epoxide using Jacobsen's catalyst
摘要：
A stereo- and enantioselective approach towards the C 1–C 16 fragment of bryostatins is reported using Jacobsen's catalyst for kinetic resolution of a terminal epoxide, a Horner–Wadsworth–Emmons coupling reaction and a 1,4-Michael type cyclization as key steps.
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DOI：
10.1016/S0040-4039(01)00841-3
被引量：
年份：
2001
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