摘要：

Secondary, but second to none: The use of secondary alkyl halides in transition‐metal‐catalyzed cross‐coupling reactions (see scheme) has advanced significantly over the last five years. Selected examples of these transformations are examined, including mechanistic and stereochemical aspects. <img class="figure__image" src="https://wol-prod-cdn.literatumonline.com/cms/attachment/3204fd4b-b03c-419d-964a-f4ea33c07adc/mcontent.gif" data-lg-src="https://wol-prod-cdn.literatumonline.com/cms/attachment/6aff3402-663c-4c04-9d6a-4e05d47a134b/mcontent.jpg">

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