Synthesis of C-3-symmetric nano-sized Polyaromatic compounds by trimerization and Suzuki-Miyaura cross-coupling reactions
摘要：
Various C 3 -symmetric molecules were prepared by trimerization of acetyl aromatic compounds and subsequently coupled with various boronic acids under Pd 0 catalysis conditions to generate oligoaryl/-heteroaryl C 3 -symmetric molecules. Several furan- and thiophene-containing star-shaped molecules were prepared by the use of SuzukiMiyaura cross-coupling as a key step. Structural and conformational details were explored by semi-empirical molecular orbital theory using the AM1 method. ( Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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DOI：
10.1002/ejoc.200400257
被引量：
年份：
2004
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