Transition-metal-promoted reactions of boron hydrides. 9. Cp*Ir-catalyzed reactions of polyhedral boranes and acetylenes

阅读量:

35

作者:

MGL MirabelliLG Sneddon

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摘要:

The complex ((C 5 Me 5 )IrCl 2 ) 2 in the presence of a proton sponge is found to catalyze reactions of pentaborane(9) (I) with terminal and internal acetylenes (II), resulting in the formation of the alkenylpentaboranes (III).

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DOI:

10.1002/chin.198818228

被引量:

235

年份:

1988

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