Novel reactivities of iodosylbenzene in the catalytic oxygenation of olefins
摘要：
Oxygenation of (carbonyl)osmium porphyrins provides trans -dioxoosmium(VI) porphyrins, which catalyze the reaction of olefins with iodosylarenes. The main reaction pathway is oxidative double bond cleavage, presumably through a hepta-coordinated osmium intermediate. Iodosylbenzene was also discovered to be an excellent initiator for the aerobic epoxidation of olefins in the presence of aldehydes under very mild reaction conditions.
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DOI：
10.1016/S1381-1169(98)00329-X
被引量：
年份：
1999
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2006
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