Concerted bimolecular substitution reactions of 1-phenylethyl derivatives

John，P.，Richard，... - 《Journal of the American Chemical Society》

Inductivity and bridging in carbocations

Publication » Inductivity and bridging in carbocations.

Grob，A Cyril - 《Accounts of Chemical Research》

Quantitative measures of solvent polarity.

The quantative scales and models, to describe the solvent polarity on chemical reactivity and physical properties of compounds, in condensed media were dev...

AR Katritzky，CF Dan，H Yang，... - 《Chemical Reviews》

Electrophilic Bromination of Carbon—Carbon Double Bonds: Structure, Solvent and Mechanism

This chapter discusses the experimental conditions, under which it is possible to obtain data relevant to the study of the bromination mechanism, and prese...

Marie-Franoise Ruasse - 《Advances in Physical Organic Chemistry》

Correlation of the rates of solvolysis of phenylchloroformate

The specific rates of solvolysis of phenyl chloroformate in 21 solvents can be very well correlated using the extended Grunwald–Winstein equation, with in...

DN Kevill，MJ D’Souza - 《Journal of the Chemical Society》

SN2 Mechanism for Alcoholysis, Aminolysis, and Hydrolysis of Acetyl Chloride

First-order solvolysis rate constants are reported for solvolyses of acetyl chloride in methanol and MeOD, and in binary aqueous mixtures with acetone, acetonitrile, ethanol, methanol, and trifluoroethanol at 0 掳C. Product selectivities...

T.，William，Bentley，... - 《Journal of Organic Chemistry》

Short communication. Solvolysis of some benzylic and non‐benzylic tertiary p‐nitrobenzoates. A new YBnOPNB scale

A new Y scale for the correlation of solvolytic reactivities for benzylic ρ-nitrobenzoates was established based on rate data for 2-phenyl-2-adamantyl ρ-nitrobenzoate, and from which the solvent assistance in the solvolysis of tert-cum...

K Liu，H Chen，C Chin - 《Journal of Physical Organic Chemistry》

What is the stabilizing interaction with nucleophilic solvents in the transition state for solvolysis of tertiary derivatives: nucleophilic solvent partici...

[structure: see text] We propose that controversy concerning the mechanism for solvolysis at tertiary carbon is semantic and can be avoided by making a cle...

JP Richard，MM Toteva，TL Amyes - 《Organic Letters》

Application of the Extended Grunwald-Winstein Equation to Solvolyses of n-Propyl Chloroformate

Application of the extended Grunwald-Winstein equation to solvolyses of n-propyl chloroformate in a variety of pure and binary solvents indicates an additi...

BK Jin，W Hoshik，DN Kevill - 《International Journal of Molecular Sciences》

Kinetics of the Solvolyses of Benzhydryl Derivatives: Basis for the Construction of a Comprehensive Nucleofugality Scale

A series of 21 benzhydrylium ions (diarylmethylium ions) are proposed as reference electrofuges for the development of a general nucleofugality scale, wher...

Denegri，Bernard; Andre，Streiter; Ofial，... - Chemistry - A European Journal