Baeyer-Villiger Oxidation of Cyclohexanone with Molecular Oxygen in the Presence of Benzaldehyde
摘要：
The metal-catalyzed Baeyer-Villiger oxidation of cyclohexanone with molecular oxygen (latm) in the presence of benzaldehyde gives -caprolactone in high yield. The same oxidation in the absence of metal catalysts is also studied. Additives to the system can improve the reaction highly efficiently.
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关键词：
vinylogous glyoxylate sesterpenoid pharmacophore PLA(2) inhibitor pericyclic selectivity bisacetals bicyclic
DOI：
10.1080/00397919608003530
被引量：
年份：
1996
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