ChemInform Abstract: Rhodium‐Catalyzed ipso‐Borylation of Alkylthioarenes via C—S Bond Cleavage.
摘要:
Rhodium-catalyzed transformation of alkyl aryl sulfides into arylboronic acid pinacol esters via C–S bond cleavage is reported. In combination with transition-metal-catalyzed sulfanyl group-guided regioselective C–H borylation reactions of alkylthioarenes, this method allows the synthesis of a diverse range of multisubstituted arenes.
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关键词:
organo‐boron compounds hydroboration, boration desulfuration, desulfonation catalysis, phase‐transfer catalysis
DOI:
10.1002/chin.201642191
被引量:
年份:
2016
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