Transition Metal Catalysed Diboration
摘要：
Homogeneous transition metal catalysed hydroboration reactions are discussed briefly, providing the background which led to the recent discovery of metal catalysed diborations [additions of the B–B bond in B2(OR)4 compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and ,βunsaturated ketones. Catalysed additions of B–Si and B–Sn bonds are also presented. Metal catalysed synthesis of organoboron compounds is a useful new synthetic method.
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关键词：
diboration hydroboration boron platinum rhodium palladium transition metal homogeneous catalysis boronate ester arylboronate
DOI：
10.1023/A:1019145818515
被引量：
年份：
1998
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