Effect of the Structure of N-Aminoalkyl(meth)acrylamides on Their Basicity in Aqueous Solutions

阅读量:

17

作者:

OA KazantsevKV ShirshinSA KazakovSM Danov

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摘要:

pKa values for a series of aminoalkyl(meth)acrylamides in aqueous water solutions were determined by potentiometric titration. The basicity of the amides increases with increasing hydrocarbon chain length between the amino- and amido groups. Taft constants σ*) of the (meth)acrylamido fragments are calculated. A correlation between the pKa values and the constants of the substituents at the amino nitrogen atom is revealed.

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年份:

1996

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