Stability quotients of some lanthanide cryptates in aqueous solutions
摘要:
Titrimetric methods were used to measure the stabilities in water of a number of cryptates of the types (Ln/sup 3 +/(Cryp)2.1.1), (Ln/sup 3 +/(Cryp)2.2.1), and (Ln/sup 3 +/(Cryp)2.2.2), where Ln represents various lanthanide elements. The results established the stability of these trivalent lanthanide complexes relative to those of lower valences and have shown that there is only a small effect of the variation of cation size among the lanthanides.
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关键词:
inorganic, organic, physical and analytical chemistry rare earth complexes stability aqueous solutions ligands valence complexes dispersions mixtures solutions 400201* -- chemical & physicochemical properties
DOI:
10.1021/ic50216a056
被引量:
年份:
1981
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