Phosphorus–carbon bond formation in dimolybdenum alkyne complexes induced by oxidative addition of chlorodiphenylphosphine
摘要：
The reaction of [Mo2(CO)4(µ-R1C2R2)(η-C5H5)2](R1,R2= H, alkyl, or aryl) with PPh2Cl proceeds via P–Cl bond cleavage and coupling of the diphenylphosphido group with the alkyne in one of three different ways depending on the nature of R1 and R2; two of the resulting complexes, [Mo2(µ-Cl){µ-Ph2PC(H)CH}(CO)2(η-C5H5)2] and [Mo2Cl2(µ-PPh2PCCHMe)(η-C5H5)2] have been characterised by X-ray analysis.
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DOI：
10.1039/C39890000688
被引量：
年份：
1989
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