ChemInform Abstract: Diastereo‐ and Enantioselective Conjugate Addition of 3‐Substituted Oxindoles to Nitroolefins Catalyzed by a Chiral Ni(OAc)2‐Diamine Complex under Mild Conditions.
摘要:
A wide range of aromatic nitroolefins and various substituted oxindoles are effectively converted to the optically enriched 3,3-disubstituted products bearing 2 vicinal quaternary/tertiary stereocenters.
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关键词:
indole derivatives, isoindole derivatives catalysis, phase‐transfer catalysis diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism
DOI:
10.1002/chin.201206103
被引量:
年份:
2012
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