In the Arena of Enantioselective Synthesis, Titanium Complexes Wear the Laurel Wreath
摘要：
An overview is given of the impressive amount of enantioselective synthetic uses that have been found for titanium catalyst and/or reagents in the last few years, from classical reactions such as 1,2- and 1,4-additions, Diels-Alder reactions, or oxidations and reductions to new procedures such as the enantioselective nucleophilic addition of unreactive organozinc reagents to poor electrophilic ketones, or the electrophilic α-halogenation of carbonyl compounds. Completely new reactions have been exclusively promoted by titanium complexes. The economical, health, and environmental benefits compared to the use of other metal-based procedures are very significant.
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关键词：
organic chemistry, review diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism organo-titanium compounds
DOI：
10.1021/cr040698p
被引量：
年份：
2006
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