Double-coupling of dibromo arenes with aryltriolborates for synthesis of diaryl-substituted planar frameworks
摘要:
A new method for simple and practical synthesis of diaryl-substituted arenes using potassium aryltriolborates was developed. Double-cross-coupling of dibromo arenes with aryltriolborates was carried out in the presence of a palladium catalyst, such as Pd(OAc) 2, Pd(PPh 3) 4 or Pd(OAc) 2/BIPHEP. The use of CuCl (40mol%) with a palladium catalyst was found to be highly effective to give diaryl-substituted aromatic compounds in good yields.
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DOI:
10.1016/j.tet.2011.06.083
被引量:
年份:
2012





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