Functional group directed C–H borylation
摘要：
The direct borylation of hydrocarbons via C–H activation has reached an impressive level of sophistication and efficiency, emerging as a fundamental tool in synthesis because of the versatility offered by organoboron compounds. As a remarkable particularity, the catalytic systems originally developed for these reactions are relatively insensitive to directing effects, and the regioselectivity of the borylations is typically governed by steric factors. Likely stimulated by the great synthetic potential of the expected functionalised organoboranes, however, many groups have recently focused on the development of complementary strategies for directed, site-selective borylation reactions where a directing group controls the course of the reaction. In this tutorial review, the different strategies and findings related to the development of these directed borylation reactions via C(sp2)–H or C(sp3)–H activation will be summarized and discussed.
展开
DOI：
10.1039/C3CS60418G
被引量：
年份：
2014
国家科技图书文献中心
(权威机构)
掌桥科研
Semantic Scholar
万方医学
dx.doi.org
查看更多
Ingenta
RSC publishing
NCBI
Europe PMC
NCBI
ResearchGate
EBSCO
hdl.handle.net
digital.csic.es
(全网免费下载)
idus.us.es
(全网免费下载)
mendeley.com
digital.csic.es
chemeurope.com
学术范
xlink.rsc.org
pubfacts.com
chemie.de
core.ac.uk
(全网免费下载)
www.socolar.com
学术范
(全网免费下载)
通过文献互助平台发起求助，成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
