Crystal structure of Cs 8 [α-BW 12 O 40 ][RhCl 6 ]·5·5H 2 O double salt
摘要：
By heating in the air [HBW 11 O 39 ] 8 with [Rh 2 (CH 3 COO) 4 (H 2 O) 2 ] in the excess of tungstate followed by crystallization in the presence of CsCl, a double salt of Cs 8 [6h-BW 12 O 40 ][RhCl 6 ]·5.5H 2 O is obtained and structurally characterized. Its crystal structure is determined by single crystal X-ray diffraction. The structure is ionic with Cs + cations, [BW 12 O 40 ] 5 anions with the Keggin structure, and [RhCl 6 ] 3 octahedral anions.
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DOI：
10.1007/s10947-010-0152-6
年份：
2010
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来源期刊
Journal of Structural Chemistry
2010/10/01
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