{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ N ,O,S}diphenyltin(IV)
摘要:
The asymmetric unit of the title compound, [Sn(C6H5)2(C12H9N3OS)], contains two independent molecules with almost identical configurations. In each molecule, the SnIV atom is coordinated by O, N and S atoms from a (2-oxido-1-naphthaldehyde)thiosemicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal–bipyramidal geometry. Weak intermolecular N—H⋯O and N—H⋯S hydrogen bonds link four molecules into a centrosymmetric tetramer. The crystal packing exhibits short intermolecular S⋯S contacts of 3.335 (3) Å.
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DOI:
10.1107/S1600536810054024
被引量:
年份:
2011
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