{1-[(2-Oxidonaphthalen-1-yl)methylidene]thiosemicarbazidato-κ N ,O,S}diphenyl­tin(IV)

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17

作者:

J CuiR HongY QiaoH Yin

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摘要:

The asymmetric unit of the title compound, [Sn(C6H5)2(C12H9N3OS)], contains two independent mol­ecules with almost identical configurations. In each mol­ecule, the SnIV atom is coordinated by O, N and S atoms from a (2-oxido-1-naph­thaldehyde)­thio­semicarbazonato ligand and two C atoms from phenyl rings in a distorted trigonal–bipyramidal geometry. Weak inter­molecular N—H⋯O and N—H⋯S hydrogen bonds link four mol­ecules into a centrosymmetric tetra­mer. The crystal packing exhibits short inter­molecular S⋯S contacts of 3.335 (3) Å.

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DOI:

10.1107/S1600536810054024

被引量:

2

年份:

2011

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2011
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