Chiral discrimination in liquids II. Excess molar enthalpies of {(1 x)A+ + xA}, where A denotes fenchone or α-methylbenzylamine
摘要：
Small but definite chiral discrimination is revealed by measurements of the excess molar enthalpy H m E of the liquid (+) and (−) enantiomers of fenchone and of α-methylbenzylamine. For fenchone H m E is negative at 303.11 K; for α-methylbenzylamine H m E is positive at 303.11 K and though still positive at 313.11 K appears to be about to change sign and become negative at temperatures above approximately 340 K.
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DOI：
10.1016/0021-9614(83)90155-6
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年份：
1983
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