Synthesis of azolyl-substituted derivatives of 1-adamantanecarboxylic acid
摘要：
Ligands containing azole rings are interesting as ligands for coordination chemistry, especially as building blocks for metal-organic frameworks. Adamantane can serve as a rigid linker for the construction of multidentate ligands. In this work we describe the synthesis of 3-azolyl-1-adamantanecaroboxylic acid derivatives starting from 3-bromo-1-adamantanecaroboxylic acid and the corresponding azoles (pyrazole, imidazole, 1,2,4-triazole, benzimidazole, 1,2,3-benzotriazole). The structure of products was confirmed by NMR and mass-spectrometry.
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DOI：
10.3390/ecsoc-20-a053
年份：
2016
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