C–H Activation for the Construction of C–B Bonds.
摘要:
The article focuses on the functionalization of carbon (C)—hydrogen (H) for C—boron (B) bonds. It discusses the borylation of arenes and alkanes in which it says that barriers for the C—H bond cleavage and the formation of B—C bond during borylation are credited to the combination of ó-donor properties of boryl and the existence of unoccupoied p[<sub>s</sub>-orbital on boron. It mentions that borylation of aryl C—H bonds take place in mild conditions.
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2010
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2010
被引量:52
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