Fischer Indole Synthesis with Organozinc Reagents
摘要:
Updated classic: Primary and secondary alkylzinc reagents add to various aryldiazonium salts leading regioselectively to polyfunctional indoles by means of a [3,3]-sigmatropic shift and subsequent aromatization. This organometallic variation of the Fischer indole synthesis tolerates a wide range of functional groups and displays absolute regioselectivity.
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DOI:
10.1002/anie.201005319
被引量:
年份:
2010
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