Pd-Catalyzed Synthesis of Isoquinolinones and Analogues via C.lb.H and N.lb.H Bonds Double Activation
摘要：
An atom economical synthesis of isoquinolinones and analogues via ligand-free Pd-catalysed C-H and N-H double activation has been developed. A series of isoquinolinones were obtained in good to excellent yields. Good regioselectivities were also observed during the activation reactions with unsymmetrical alkynes. A practical one-pot procedure for the preparation of N-H isoquinolinones is also described.
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DOI：
10.1039/C2CC17859A
被引量：
年份：
2012
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