Copper-catalyzed highly regio- and stereoselective directed hydroboration of unsymmetrical internal alkynes: controlling regioselectivity by choice of catalytic species.
摘要：
Taking control of boron: A highly regio- and stereoselective copper-catalyzed hydroboration of unsymmetrical internal alkynes has been developed. The regioselectivity was successfully controlled by the choice of catalytic species (copper hydride or boryl copper; see scheme).
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DOI：
10.1002/chem.201103612
被引量：
年份：
2012
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