Synthesis of oxindoles by iron-catalyzed oxidative 1,2-alkylarylation of activated alkenes with an aryl C(sp2)-H bond and a C(sp3)-H bond adjacent to a heteroatom.
摘要：
Difunctionalization: Inexpensive and environmentally benign FeCl3 catalyzes the oxidative 1,2-alkylarylation of activated alkenes with an aryl C(sp2)H bond and a C(sp3)H bond adjacent to a heteroatom. This reaction is a new strategy for the synthesis of oxindoles and makes use of DBU as ligand and TBHP as oxidant (see scheme, TBHP=tert-butyl hydrogenperoxide).
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DOI：
10.1002/anie.201210029
被引量：
年份：
2013
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来源期刊
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2014
被引量：222
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