摘要：

Tomato source: 12‐Oxophytodienoate reductase isoenzymes OPR1 and OPR3 from tomato possess a broad substrate spectrum for the asymmetric bioreduction of α,β‐unsaturated enals, enones, dicarboxylic acids, and N‐substituted maleimides (see scheme). Stereocomplementary behavior of both isoenzymes was observed in the reduction of a nitroalkene that led to the formation of opposite stereoisomers in high enantiomeric excess. <img class="figure__image" src="https://wol-prod-cdn.literatumonline.com/cms/attachment/36f31bd7-88b8-4c65-9894-34e81bf2ba73/mcontent.gif" data-lg-src="https://wol-prod-cdn.literatumonline.com/cms/attachment/851edf0d-2ec1-4887-81ed-01b2e8077449/mcontent.jpg">

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