Diastereoselective synthesis of dispiro[indoline-3,1'-cyclobutane-2',3"-indolines] via visible light catalyzed cyclodimerization of 3-phenacylideneoxindoles.

阅读量:

17

作者:

Yan-HongJiangRen-YinYangJingSunChao-GuoYan

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摘要:

A simple synthetic protocol was developed for the efficient synthesis of functionalized dispiro[indoline-3,1'-cyclobutane-2',3"-indolines] with high diastereoselectivity. The reaction proceeds by cyclodimerization reaction of 3-phenacylideneoxindoles in the presence of a catalytic amount of photosensitizer Ru(bpy<SUB>3</SUB>)Cl<SUB>2</SUB> and visible light.

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DOI:

10.1515/hc-2016-0022

年份:

2016

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