A New Copper Acetate-Bis(oxazoline)-Catalyzed, Enantioselective Henry Reaction

阅读量:

44

作者:

DavidA.EvansDanielSeidelMagnusRuepingHonWaiLam

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摘要:

A highly enantioselective, nitroaldol reaction catalyzed by a chiral Cu(II) bis(oxazoline) complex has been developed. The reaction scope includes both aromatic and aliphatic aldehydes (15 examples) affording products in good yields and enantioselectivities (87−94% ee). An X-ray structure of the catalyst has been provided along with a rationalization of the sense of asymmetric induction.

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DOI:

10.1021/ja0373871

被引量:

920

年份:

2003

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2010
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