摘要：

(Triazolinylidene)rhodium(COD) complexes 1–3 containing an axis of chirality have been prepared with de=91–97%. The application of these complexes as catalysts in an asymmetric hydrosilylation reaction of methyl ketones 4–7 has been investigated, resulting in an ee of up to 44%. A non-linear temperature effect ('principle of isoinversion') has been examined.

展开