Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.
摘要：
The catalytic hydroboration oftert-butylethene using H3B·NMe3gives RH2B·NMe3. With H3B·NMe2H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R2BNMe2(R = H, CH2CH2tBu).
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关键词：
1,3,5-Triazapentadienes Imidoylamidines Amination Amidines Nitrites Dicyanamidate Triazines Template synthesis
DOI：
10.1039/c1dt10819k
被引量：
年份：
2011
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2013
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